Hi vcc,
In order to create an openVPN server, you must create a CA certificate, as you did, and another certificate for the server. After doing that, you must go to "OpenVPN -> Create server" to create a new one with your desired parameters. Afterwards, you should add those networks you want your VPN clients connect to. Finally, in main OpenVPN page, clicking in download icon, you may get the bundle for your operating system (Windows or Linux|MacOS) to install it on the VPN client.
Hope this helps you a little.