I could be wrong and I hope someone mentions so before you have a chance to do anything that could cause your problems but as I have been messing with the DC settings in Zentyal recently with the changes and configuration I've been trying to implement, I have run across a command. If you type "/usr/share/zentyal/unconfigure-module samba" in a terminal at/on the machine, it will unconfigure those settings giving you an option to select DC, Additional DC, or the option to simply read the DC information. Hope this helps.