I had this same issue when setting up Zentyal as a PDC what I had to do was right my nameservers to /etc/resolv.conf and then run the command chattr +i /etc/resolv.conf
so it cant be re-written. If you need to write to it again the command is chattr -i /etc/resolv.conf
also note within your /etc/resolv.conf file, put your primary DNS server first in the list, Zentyal wants to put 127.0.0.1 first-- change this or else it will never use your DNS Nameservers.