Hi, sry to resurrect this post but just thought would share my experiences with getting usb stick install working.
I made the install stick via several methods - used ubuntu usb creator, unetbootin etc. they all worked and failed in same place.
Everything seemed to go okay until installing software, last step before installing grub. It failed at this point every time, keep with me and I will hopefully shed some light on this.
I was installing over my previous linux server installation, I decided to try and install a minimum ubuntu 12.04 LTS server. I got exactly the same problem, so I'm assuming this is not a zentyal fault but a ubuntu fault.
How I got it to work was to delete and re-make my partitions so they were clear of any old crap. I only erased the root, home and efiboot boot partition. Suddenly all worked fine and I proceeded to install zentyal-desktop ontop of my minimal ubuntu 12.04 server install.
I'm guessing zentyal 3.0 would work straight from the usb stick install using same method, just backup any important data you have on root / home partitions first.
Good luck!