Can you answer the following question: Is your Zentyal box responsible for receiving and routing all traffic from the internet?
This part is pretty clear on the provided drawing:
Zentyal is somewhere in the middle of the LAN, connecting to Internet via multiple switches and routers (wicedyrektor, airlive2) on one side and, for what I can guess, connecting classrooms 20 & 24 on the other side.
All other devices have "direct" access to internet and can't be under Zentyal's control.
However I don't think this is what this user wants to achieve. unless I'm wrong, is goal is to allow file sharing between devices and users that are not part of same domain or not even part of any domain. What I don't understand is whether this is linked to internet access or not.