If LDAP is not your friend, I would (strongly
) suggest you do not try to manually edit its content
Trust me
LDAP DIT doesn't matter that much, meaning even if your domain changed, changing your LDAP content is not 100% mandatory.
This said, would you need or want, for whatever reason, change it, the easiest and safest way is to reinstall "users & groups" Zentyal component. Well, if you have a lot of users or shared files or mailboxes, this can be tricky too.
One aspect you may have to understand: since a while, Unix/Linux relies on NSS in order to determine where to find various services. The most current source for this is "
file" but this also could be "
NIS" or "
LDAP" and stacking multiple sources is feasible, reason why you can have users in both LDAP and /etc/passwd/.